After being elected as the Chief Minister, Uddhav Thackeray expanded his cabinet on December 30, 2019, wherein Ajit Pawar was declared as the Deputy Chief Minister and Aditya Thackeray, Amit Deshmukh were some prominent names among others.
Here's the complete list of allotted portfolios to the State Minister:
| Party | Minister | Ministry |
| NCP | Ajit Pawar | Finance |
NCP | Jayant Patil | Water resources (Irrigation) |
| NCP | Anil Deshmukh | Home |
| NCP | Chhagan Bhujbal | Food, Civil |
| NCP | Dilip Walse-Patil | Excise, Labour |
NCP | Jitendra Awhad | Housing |
| NCP | Rajesh Tope | Health |
| NCP | Rajendra Shingne | Food and Drugs Administration |
NCP | Dhananjay Munde | Social Justice |
Congress | Balasaheb Thorat | Revenue |
| Congress | Ashok Chavan | Public Works Department (PWD) |
| Congress | Nitin Raut | Energy |
| Congress | Varsha Gaikwad | School Education |
| Congress | Yashomati Thakur | Women and Child Welfare |
| Congress | KC Padvi | Tribal Development |
| Congress | Sunil Kedar | Dairy development |
| Congress | Vijay Vadettiwar | OBC welfare |
| Congress | Aslam Shaikh | Textiles, Ports |
| Congress | Amit Deshmukh | Health, Education, Culture |
| Shiv Sena | Eknath Shinde | Urban Development |
| Shiv Sena | Subhash Desai | Industries |
| Shiv Sena | Sanjay Rathod | Forest |
| Shiv Sena | Dadaji Bhuse | Agriculture |
| Shiv Sena | Uday Samant | Higher and Technical Education |
| Shiv Sena | Anil Parab | Transport, Parliamentary Affairs |
| Shiv Sena | Sandipanrao Bhumre | EGS |
| Shiv Sena | Shankarrao Gadakh | Water Conservation |
| Shiv Sena | Gulrabrao Patil | Water Supply |